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163.113
Organometallic Chemistry
This course is in all assigned curricula part of the STEOP.
This course is in at least 1 assigned curriculum part of the STEOP.
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2019W, VO, 2.0h, 3.0EC, to be held in blocked form
Properties
Semester hours: 2.0
Credits: 3.0
Type: VO Lecture
Learning outcomes
After successful completion of the course, students are able to understand the electronic structure of organometallic compounds (transition metals), reactivity and stability based on MO-theory, mechanistic aspects: substitution reactions, oxidative addition reactions (e.g., H-H-, C-H-, C-Si- and C-C bond activation), reductive elimination, insertions, eliminations (alpha-, beta- and gamma-eliminations, decarbonylations, decarboxylations), sigma-bond metathesis, reaction of coordinated ligands (nucleophilic and electrophilic additions and abstractions), metallacycles, mechanistic aspects of homogeneous catalysis relevant to industrial processes (olefin hydrogenation and isomerization, hydroformylation, Wacker process, Monsanto acetic acid process, hydrosilation, C-C cross coupling reactions with Fe, Ru, Ni, and Pd complexes), stoichiometric and catalytic reactions with carbene and carbyne complexes (Tebbe reaction, olefin and alkyne metathesis), stoichiometric metal-assisted reactions, physical methods in organometallic chemistry based on NMR spectroscopy (bonding of coordinated ligands, NMR of heteronucleii, static and dynamic NMR measurements, isotope effects, T1 relaxation time measurements)
Subject of course
Electronic structure of organometallic compounds (transition metals), reactivity and stability based on MO-theory, mechanistic aspects: substitution reactions, oxidative addition reactions (e.g., H-H-, C-H-, C-Si- and C-C bond activation), reductive elimination, insertions, eliminations (alpha-, beta- and gamma-eliminations, decarbonylations, decarboxylations), sigma-bond metathesis, reaction of coordinated ligands (nucleophilic and electrophilic additions and abstractions), metallacycles, mechanistic aspects of homogeneous catalysis relevant to industrial processes (olefin hydrogenation and isomerization, hydroformylation, Wacker process, Monsanto acetic acid process, hydrosilation, C-C cross coupling reactions with Fe, Ru, Ni, and Pd complexes), stoichiometric and catalytic reactions with carbene and carbyne complexes (Tebbe reaction, olefin and alkyne metathesis), stoichiometric metal-assisted reactions, physical methods in organometallic chemistry based on NMR spectroscopy (bonding of coordinated ligands, NMR of heteronucleii, static and dynamic NMR measurements, isotope effects, T1 relaxation time measurements)
Teaching methods
Teaching content through case studies and PowerPoint presentations
Mode of examination
Oral
Lecturers
Kirchner, Karl
Institute
E163 Institute of Applied Synthetic Chemistry
Course dates
Day
Time
Date
Location
Description
Wed
10:00 - 16:00
22.01.2020
Seminarraum Lehar 03
lecture
Thu
13:00 - 18:00
23.01.2020
Seminarraum Lehar 03
lecture
Course is held blocked
Examination modalities
mündlich
Course registration
Begin
End
Deregistration end
03.10.2019 15:00
Registration modalities
Chemie-Neubau, 2. Stock, Zimmer Prof. Kirchner Ort: bei der Vorbesprechung
Curricula
Study Code
Obligation
Semester
Precon.
Info
066 490 Technical Chemistry
Mandatory elective
066 491 Technical Chemistry - Synthesis
Mandatory
Literature
No lecture notes are available.
Miscellaneous
Attendance Required!
Language
German